Cherokee Syllabary
In his system, each symbol represents a syllable rather than a single phoneme; the 85 (originally 86) characters provide a suitable method to write Cherokee. Some Cherokee words pose a problem for transliteration software because they contain adjacent pairs of single letter symbols that (without special provisions) would be combined when doing the back-conversion from Latin script to Cherokee. [19]
In 1828, the order of the characters in a chart and the shapes of the characters were modified by Cherokee author and editor Elias Boudinot to adapt the syllabary to printing presses.
Source: en.wikipedia.org